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The four-time Grand Slam champion looked solid enough on serve, with just five double-faults to eight by her opponent and she had Pavlyuchenkova under constant pressure with her booming returns.
Her opponent in the quarter-finals will be Polish top seed Agnieszka Radwanska who proved too good for Italian doubles specialist Roberta Vinci, winning 6-3, 6-2.
“Radwanska is the number three in the world and everyone knows she plays extremely well, but I love challenges like this,” said Sharapova, who leads Radwanska 8-2 in previous meetings.
“There are no secrets to our games, we know each other very well, but have not played each other for a while on clay. It will be interesting and I’ll have to improve in all areas.”
Second seeded Simona Halep squandered a 5-2 first set lead and three set points to lose 7-5, 7-6 (7/4) to former US Open and French Open champion Svetlana Kuznetsova.
Former world number one and Stuttgart champion Jelena Jankovic booked her quarter-final berth as she beat Flavia Pennetta of Italy 3-6, 6-2, 6-3, while Serb ninth seed Ana Ivanovic beat Germany’s Julia Goerges 1-6, 6-2, 6-3.
“At the end I missed the power in my game, but the positive thing is that I was able to play some good tennis despite all the travel,” said 2011 Stuttgart champion Goerges, who had played in Germany’s Fed Cup semi-final win in Australia last weekend.
Ivanovic plays Kuznetsova in the quarter-finals.
German Fourth seed Angelique Kerber, who also played Fed Cup in Australia at the weekend, went down 7-5, 6-4 to Spanish clay-courter Carla Suarez Navarro.